BaF radical: A promising candidate for laser cooling and magneto-optical trapping.

Recently, there have been great interest and advancement in the field of laser cooling and magneto-optical trapping of molecules. The rich internal structure of molecules naturally lends themselves to extensive and exciting applications. In this paper, the radical , as a promising candidate for laser cooling and magneto-optical trapping, is discussed in detail. The highly diagonal Franck–Condon factors between the and states are first confirmed with three different methods. Afterwards, with the effective Hamiltonian approach and irreducible tensor theory, the hyperfine structure of the state is calculated accurately. A scheme for laser cooling is given clearly. Besides, the Zeeman effects of the upper () and lower () levels are also studied, and their respective g factors are obtained under a weak magnetic field. Its large g factor of the upper state is advantageous for magneto-optical trapping. Finally, by studying Stark effect of BaF in the , we investigate the dependence of the internal effective electric field on the applied electric field. It is suggested that such a laser-cooled BaF is also a promising candidate for precision measurement of electron electric dipole moment. [ABSTRACT FROM AUTHOR]