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The synthesis of a silver hexagon using a diiminoisoindoline-based ligand.
- Source :
-
Inorganic Chemistry Communications . Feb2017, Vol. 76, p122-124. 3p. - Publication Year :
- 2017
-
Abstract
- Diiminoisoindoline (DII) can be modified with primary amines to afford bis-substituted heterocycles. Although the metal binding chemistry of isoindoline-based macrocycles and chelates has been explored, the corresponding chemistry of hydrocarbon substituted diiminoisoindolines remains open. The reaction of the bis(benzylimino)isoindoline with AgNO 3 affords a Ag 6 cluster complexed by four equivalents of ligand. The cluster exhibits a previously unknown argentophilic geometry. The Ag 6 unit forms a compressed hexagon, comprised of two Ag 3 triangles that are linked together to form a parallelogram. The argentophilic interactions range from ~ 2.76 to ~ 3.17 Å. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 76
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 121359325
- Full Text :
- https://doi.org/10.1016/j.inoche.2017.01.018