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Copolymerization and thermal study of the new methacrylate derivative of 2,4,6-trichlorophenol.
- Source :
-
Journal of Thermal Analysis & Calorimetry . Mar2017, Vol. 127 Issue 3, p2263-2271. 9p. - Publication Year :
- 2017
-
Abstract
- In this study, 2,4,6-trichlorophenyl methacrylate (TClPhMA) was synthesized by the reaction of methacryloyl chloride with 2,4,6-trichlorophenol in the ice bath condition. The obtained monomer was extracted by chloroform and purified on a chromatography column. In order to confirm the chemical structure of the new compound, spectroscopic studies (ATR-FTIR, H NMR, C NMR and GC-MS) were undertaken. The obtained TClPhMA was copolymerized with commercially available monomers such as methyl methacrylate, styrene, 1,4-divinylbenzene and 2-hydroxymethyl methacrylate. The copolymers were obtained by bulk polymerization in which benzoyl peroxide was used as a free radical initiator. The thermal properties of the copolymers were investigated by differential scanning calorimetry and thermogravimetry. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13886150
- Volume :
- 127
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Journal of Thermal Analysis & Calorimetry
- Publication Type :
- Academic Journal
- Accession number :
- 121301951
- Full Text :
- https://doi.org/10.1007/s10973-016-5672-7