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Freestanding MnO2 nanoflakes on carbon nanotube covered nickel foam as a 3D binder-free supercapacitor electrode with high performance.
- Source :
-
Journal of Electroanalytical Chemistry . Feb2017, Vol. 786, p35-42. 8p. - Publication Year :
- 2017
-
Abstract
- Designing and fabricating self-supported and binder-free MnO 2 nanostructure electrode to overcome their low conductivity for supercapacitor application with high comprehensive electrochemical performance, such as high capacitance, excellent stability, and good rate capability, is still a tremendous challenge. In this paper, carbon nanotubes are uniform covered on nickel foam (denote as CNT/Ni) by a simple dip & dry method to form a 3D skeleton for MnO 2 nanosheets deposition (denoted as MnO 2 -CNT/Ni). Results show the MnO 2 -CNT/Ni electrode exhibits a unique 3D porous interconnected network with a high specific capacitance of 402.5 F g − 1 at 1 A g − 1 and a favorable cycling performance that 83% capacitance retained after 5000 cycles at a current density of 2 A g − 1 . Meanwhile, the MnO 2 -CNT/Ni//CNT/Ni asymmetric supercapacitor exhibits an excellent energy density of 25 Wh kg − 1 at a power density of 0.9 kW kg − 1 with 85.3% capacitance retention after 5000 cycles. Therefore, such a facile and manageable method to prepare MnO 2 electrode with high supercapacitor performance is offering a promising future for practical applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15726657
- Volume :
- 786
- Database :
- Academic Search Index
- Journal :
- Journal of Electroanalytical Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 121067234
- Full Text :
- https://doi.org/10.1016/j.jelechem.2017.01.005