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Room temperature multiferroicity in Aurivillius compounds Bi6Fe2−xNixTi3O18 (0≤x≤1).
- Source :
-
Ceramics International . Apr2017, Vol. 43 Issue 5, p4405-4410. 6p. - Publication Year :
- 2017
-
Abstract
- We investigate the structural, magnetic, ferroelectric, and dielectric properties of Bi 6 Fe 2− x Ni x Ti 3 O 18 (0≤ x ≤1). The coexistence of ferroelectricity and ferromagnetism were observed at room temperature for the Ni-doped samples. The ferromagnetism in Bi 6 Fe 2− x Ni x Ti 3 O 18 can be understood in terms of spin canting of the antiferromagnetic coupling of the Fe-based and Ni-based sublattices via Dzyaloshinsky-Moriya interaction. Moreover, the substitution of Ni for Fe was effective for the enhancement of ferroelectric properties. The x =0.6 sample exhibits a maximum remnant polarization P r of 37.8 μC/cm 2 because of a lower leakage current. The rather large activation energy in the x =0 and 0.2 samples implies that the relaxation process may be not associated with the thermal motion of oxygen vacancies inside the bulk. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 43
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 120834434
- Full Text :
- https://doi.org/10.1016/j.ceramint.2016.12.087