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Nanocomposite organic solvent nanofiltration membranes by a highly-efficient mussel-inspired co-deposition strategy.
- Source :
-
Journal of Membrane Science . Mar2017, Vol. 526, p32-42. 11p. - Publication Year :
- 2017
-
Abstract
- Herein, a novel nanocomposite organic solvent nanofiltration (OSN) membrane has been facilely fabricated by a highly-efficient one-step co-deposition of mussel-inspired catechol and octaammonium polyhedral oligomeric silsesquioxane (POSS-NH 3 + Cl - ) onto supports. The basic properties and morphologies of the co-deposited nanocomposite membranes were investigated with various physicochemical characterizations in detail. Attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectra proved the present of POSS nanoparticles on membrane surface. X-ray photoelectron (XPS) results suggested the optimal ratio of POSS-NH 3 + Cl - and catechol for co-deposition. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) images demonstrated the formation of a layer on support surface. The optimized nanocomposite membrane exhibited an ethanol (EtOH) permeance of 1.26 L m −2 h −1 bar −1 with a rejection of 99% to Rose Bengal (RB). The novel membrane also exhibited remarkable separation performance for dyes removal from a wide range of solvents including challenging polar aprotic and strongly swelling solvents. Particularly, the nanocomposite membrane demonstrated stable performances during a two-day long term test in DMF for RB concentration. In addition to providing a highly-efficient way to high-performance OSN membrane, this work may stimulate the bio-inspired design of advanced nanocomposite membranes for environmental applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03767388
- Volume :
- 526
- Database :
- Academic Search Index
- Journal :
- Journal of Membrane Science
- Publication Type :
- Academic Journal
- Accession number :
- 120776281
- Full Text :
- https://doi.org/10.1016/j.memsci.2016.12.026