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What are the differences between Hantzsch ester and H2 as two-hydrogen-atom donors in acetonitrile on the thermodynamics of elementary steps?
- Source :
-
Journal of Physical Organic Chemistry . Feb2017, Vol. 30 Issue 2, pn/a-N.PAG. 5p. - Publication Year :
- 2017
-
Abstract
- Thermodynamic driving forces of eight possible elementary steps for Hantzsch ester and six possible elementary steps for H2 to release two hydrogen atoms (2H•) or ions (H− and H+) in acetonitrile were examined using experimental method or the available related thermodynamic data for the first time, which can facilitate chemists to choose a suitable reducing agent between Hantzsch ester and H2 to reduce a given organic unsaturated compound in acetonitrile and make a rational diagnosis on the detailed reaction mechanisms. The focus of this paper is to compare the differences between Hantzsch ester and H2 to release two hydrogen atoms (or ions) on the thermodynamics of elementary steps in acetonitrile. Copyright © 2016 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 08943230
- Volume :
- 30
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Journal of Physical Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 120690935
- Full Text :
- https://doi.org/10.1002/poc.3599