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Stable, crystalline boron complexes with mono-, di- and trianionic formazanate ligands.
- Source :
-
Chemical Communications . 1/11/2017, Vol. 53 Issue 3, p513-516. 4p. - Publication Year :
- 2017
-
Abstract
- Redox-active formazanate ligands are emerging as tunable electron-reservoirs in coordination chemistry. Here we show that boron diphenyl complexes with formazanate ligands, despite their (formal) negative charge, can be further reduced by up to two electrons. A combined crystallographic, spectroscopic and computational study establishes that formazanate ligands are stable in mono-, di- and trianionic form. [ABSTRACT FROM AUTHOR]
- Subjects :
- *LIGANDS (Chemistry)
*COORDINATION compounds
*BORON
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 53
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 120541065
- Full Text :
- https://doi.org/10.1039/c6cc08166e