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ChemInform Abstract: Giant Hollow Heterometallic Polyoxoniobates with Sodalite-Type Lanthanide-Tungsten-Oxide Cages: Discrete Nanoclusters and Extended Frameworks.
- Source :
-
ChemInform . Dec2016, Vol. 47 Issue 52, pno-no. 1p. - Publication Year :
- 2016
-
Abstract
- A series of Nb-W-Ln heterometallic polyoxometalates {Ln12W12O36(H2O)24 (Nb6O19)12} (Ln: Y, La, Sm, Eu, Yb) is prepared by e.g. hydrothermal reaction of K7HNb6O19, Na2WO4, Cu(OAc)2, SmCl3, trimesic acid, and en in a carbonate buffer at pH 10.5 (autoclave, 160 °C, 72 h, 70% yield). [ABSTRACT FROM AUTHOR]
- Subjects :
- *POLYOXOMETALATES
*TRIMESIC acid
*SODIUM tungstate
Subjects
Details
- Language :
- English
- ISSN :
- 09317597
- Volume :
- 47
- Issue :
- 52
- Database :
- Academic Search Index
- Journal :
- ChemInform
- Publication Type :
- Academic Journal
- Accession number :
- 120215340
- Full Text :
- https://doi.org/10.1002/chin.201652026