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Macroscopic Hexagonal Tubes of 3 d -4 f Metallocycles.

Authors :
Wu, Jianfeng
Zhao, Lang
Zhang, Li
Li, Xiao ‐ Lei
Guo, Mei
Powell, Annie K.
Tang, Jinkui
Source :
Angewandte Chemie. 12/12/2016, Vol. 128 Issue 50, p15803-15807. 5p.
Publication Year :
2016

Abstract

The self-assembly of three giant hexagonal 3d-4f metallocycles with inner diameters of 16.4, 16.5, and 16.4 Å, is described. Hexagonal metallocycles were stacked along the crystallographic c axis, producing unique hexagonal macroscopic tubular single crystals. The assembly mechanism of the tubular crystals was investigated. Remarkably, all three hexagonal metallocycles show typical single-molecule magnet behavior, benefiting from the ferromagnetic couplings between the 3d and 4f ions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00448249
Volume :
128
Issue :
50
Database :
Academic Search Index
Journal :
Angewandte Chemie
Publication Type :
Academic Journal
Accession number :
119975082
Full Text :
https://doi.org/10.1002/ange.201609539