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Pd-catalyzed ligand-free C(5)–H arylation of 1,4-disubstituted 1,2,3-triazoles promoted by microwaves.
- Source :
-
Synthetic Communications . 2016, Vol. 46 Issue 20, p1678-1686. 9p. 5 Diagrams, 1 Chart. - Publication Year :
- 2016
-
Abstract
- Pd(OAc)2-catalyzed regioselective C(5)–H arylation of 1,4-disubstituted 1,2,3-triazoles was achieved without ligand under microwave conditions in 1 h, generating 1,4,5-trisubstituted 1,2,3-triazoles with good to excellent yields. The obtained molecules can be easily converted into 4,5-disubstituted 1,2,3-triazoles through the debenzylation process with one-pot manipulation. [ABSTRACT FROM PUBLISHER]
Details
- Language :
- English
- ISSN :
- 00397911
- Volume :
- 46
- Issue :
- 20
- Database :
- Academic Search Index
- Journal :
- Synthetic Communications
- Publication Type :
- Academic Journal
- Accession number :
- 119359740
- Full Text :
- https://doi.org/10.1080/00397911.2016.1222441