Back to Search
Start Over
Synthesis of Hierarchically Porous Sandwich-Like Carbon Materials for High-Performance Supercapacitors.
- Source :
-
Chemistry - A European Journal . 11/14/2016, Vol. 22 Issue 47, p16863-16871. 9p. - Publication Year :
- 2016
-
Abstract
- For the first time, hierarchically porous carbon materials with a sandwich-like structure are synthesized through a facile and efficient tri-template approach. The hierarchically porous microstructures consist of abundant macropores and numerous micropores embedded into the crosslinked mesoporous walls. As a result, the obtained carbon material with a unique sandwich-like structure has a relatively high specific surface (1235 m2 g−1), large pore volume (1.30 cm3 g−1), and appropriate pore size distribution. These merits lead to a comparably high specific capacitance of 274.8 F g−1 at 0.2 A g−1 and satisfying rate performance (87.7 % retention from 1 to 20 A g−1). More importantly, the symmetric supercapacitor with two identical as-prepared carbon samples shows a superior energy density of 18.47 Wh kg−1 at a power density of 179.9 W kg−1. The asymmetric supercapacitor based on as-obtained carbon sample and its composite with manganese dioxide (MnO2) can reach up to an energy density of 25.93 Wh kg−1 at a power density of 199.9 W kg−1. Therefore, these unique carbon material open a promising prospect for future development and utilization in the field of energy storage. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 22
- Issue :
- 47
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 119336032
- Full Text :
- https://doi.org/10.1002/chem.201603145