Back to Search Start Over

A monocyclic neodysiherbaine analog: Synthesis and evaluation.

Authors :
Fukushima, Koichi
Ishikawa, Yuichi
Sakai, Ryuichi
Oikawa, Masato
Source :
Bioorganic & Medicinal Chemistry Letters. Nov2016, Vol. 26 Issue 21, p5164-5167. 4p.
Publication Year :
2016

Abstract

Monocyclic analog of neuroexcitatory neodysiherbaine has been designed and stereoselectively synthesized in 0.40% yield over total 24 steps starting from d -ribose, by employing domino aldol-Cannizzaro reaction and stereoselective aldol reaction for construction of two quaternary carbon stereogenic centers at C4 and C6 positions, respectively. The hyperactivity of neodysiherbaine in mice was found to deteriorate in the novel analog, upon intracerebroventricular injection. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
0960894X
Volume :
26
Issue :
21
Database :
Academic Search Index
Journal :
Bioorganic & Medicinal Chemistry Letters
Publication Type :
Academic Journal
Accession number :
119002446
Full Text :
https://doi.org/10.1016/j.bmcl.2016.09.074