Back to Search
Start Over
Olefin/Paraffin Separation Potential of ZIF-9 and ZIF-71: A Combined Experimental and Theoretical Study.
- Source :
-
European Journal of Inorganic Chemistry . Sep2016, Vol. 2016 Issue 27, p4440-4449. 10p. - Publication Year :
- 2016
-
Abstract
- Two zeolitic imidazolate frameworks, ZIF-9 and ZIF-71, are evaluated by adsorption experiments and molecular simulations with respect to their potential towards olefin/paraffin separation. Pure component adsorption isotherms are measured and compared to grand-canonical Monte-Carlo (GCMC) simulations. The experiments show that the adsorption of the paraffin is favorable over the olefin in both structures. Whereas the isotherms are predicted well by simulations for ZIF-71, in case of ZIF-9 only the saturation loading could be computed accurately because the latter material seems to undergo a so-called gate-opening effect upon adsorption of guest molecules; ZIF-71 does not show this effect. Both structures show promising results with respect to olefin/paraffin separation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14341948
- Volume :
- 2016
- Issue :
- 27
- Database :
- Academic Search Index
- Journal :
- European Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 118352953
- Full Text :
- https://doi.org/10.1002/ejic.201600695