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Extraction behaviors of uranyl peroxo cage clusters by mesoporous silica SBA-15.
- Source :
-
Journal of Radioanalytical & Nuclear Chemistry . Oct2016, Vol. 310 Issue 1, p453-462. 10p. 1 Color Photograph, 6 Charts, 5 Graphs. - Publication Year :
- 2016
-
Abstract
- Sorption of soluble uranyl peroxo cage clusters (U60 [UO(O)(OH)] and U24Pp [(UO)(O)(PO)]) by mesoporous sorbent SBA-15 has been studied. Sorption kinetics of U60 and U24Pp are both best described by a pseudo-second-order model. However, only in the U60 sorption, intraparticle diffusion is the rate-determining step, and both pore size and pore volume of SBA-15 positively influence the U sorption capacity. Sorption isotherms of U60 and U24Pp are better fitted by the Langmuir and Freundlich isotherm models, respectively. The differences of sorption behaviors between two clusters by SBA-15 may result from differences of the sizes and terminal ligands of the clusters. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02365731
- Volume :
- 310
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of Radioanalytical & Nuclear Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 118120872
- Full Text :
- https://doi.org/10.1007/s10967-016-4801-x