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Structural Proof for the First Dianion of a Polychloride: Investigation of [Cl8]2−.
- Source :
-
Angewandte Chemie International Edition . 8/26/2016, Vol. 55 Issue 36, p10904-10908. 5p. - Publication Year :
- 2016
-
Abstract
- The polychloride salt [CCl(NMe2)2]+2[Cl8]2− was synthesized and crystallized in the ionic liquid [BMP]OTf. The compound was fully characterized by Raman spectroscopy as well as X-ray single-crystal structure determination, and represents the first example of a polychloride dianion to be described. Detailed gas-phase and solid-state calculations concerning the nature of the bonding situation were also performed. [ABSTRACT FROM AUTHOR]
- Subjects :
- *IONIC liquids
*CRYSTALLIZATION
*CHEMICAL synthesis
*SALT
*CHEMICAL reactions
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 55
- Issue :
- 36
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 117630713
- Full Text :
- https://doi.org/10.1002/anie.201604348