A comparative study on textural characterization: cation-exchange and sorption properties of crystalline <f>α</f>-zirconium(IV), tin(IV), and titanium(IV) phosphates

Tetravalent metal phosphates (<f>M=Zr</f>, Ti, and Sn) were prepared and characterized by XRD, surface properties, and TG-DTA. The cation exchange and sorption behavior of these metal phosphates toward transition metal ions such as Cu<f>2+</f>, Co<f>2+</f>, and Ni<f>2+</f> have been studied comparatively as a function of temperature and concentration. The adsorption process was found to increases with increase in temperature and concentration. The selectivity order for <f>α</f>-titanium and <f>α</f>-tin phosphates is <f>Cu2+>Co2+>Ni2+</f>, whereas for <f>α</f>-zirconium phosphate it is <f>Cu2+>Ni2+>Co2+</f>. The ion exchange capacity of <f>α</f>-titanium phosphate is greater than those of other phosphates, which is explained on the basis of the surface behavior, disorderness of the system, degree of hydrolysis of incoming guest adsorbate metal ions, and structural steric hindrance of the exchangers during adsorption and sorption. The distribution coefficient, Gibbs free energy, enthalpy, and entropy values indicate that the ion-exchange processes are spontaneous. [Copyright &y& Elsevier]