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Highly Thermostable, Non-oxidizable Indium, Gallium, and Aluminium Perfluorophthalocyanines with n-Type Character.
- Source :
-
Chemistry - A European Journal . 8/16/2016, Vol. 22 Issue 34, p12050-12060. 11p. - Publication Year :
- 2016
-
Abstract
- Perfluorophthalocyanines incorporating three-valent metals, namely In(Cl), Ga(Cl), and Al(Cl), have been synthesized and characterized. Thermogravimetric analysis revealed that these compounds exhibit outstanding thermal stability and a tendency to sublime at a temperature exceeding around 350 °C without thermal decomposition. Cyclic voltammetry (CV) and differential pulse voltammetry (DPV) were used to probe the frontier orbital energy levels of these compounds in THF solution. All three compounds undergo three quasi-reversible reductions with the first one leading to the formation of an anion radical, namely MPc−., as confirmed by spectroelectrochemistry. The compounds studied were intrinsically resistive to oxidation, which indicates that they are very good electron acceptors (n-type materials). The HOMO-LUMO energy gaps ( Eg) of the three compounds determined by UV/Vis spectroscopy were relatively unaffected by the three-valent metals incorporated into the phthalocyanine macrocycle. Similarly, the energies of the HOMO ( EHOMO) and LUMO ( ELUMO) orbitals remained virtually unaffected by the three-valent metals in the perfluorophthalocyanine. Importantly, all the perfluorophthalocyanines studied possess LUMO levels between −4.76 and −4.85 eV, which makes their reduced forms resistant to electron trapping by O2 and H2O. This property opens up the possibility for the fabrication of electronic devices operating under ambient conditions. All three compounds demonstrated very good photostability as solid thin films. [ABSTRACT FROM AUTHOR]
- Subjects :
- *INDIUM
*GALLIUM
*METALS
*SOLID state electronics
*ELLIPSOMETRY
Subjects
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 22
- Issue :
- 34
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 117300918
- Full Text :
- https://doi.org/10.1002/chem.201601386