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Iron(0) mediated C–H activation of 1-hexyne: a mechanistic study using time-resolved infrared spectroscopy.

Authors :
Blank, Jan H.
Raju, Rajesh K.
Yan, Tao
Brothers, Edward N.
Darensbourg, Marcetta Y.
Bengali, Ashfaq A.
Source :
Dalton Transactions: An International Journal of Inorganic Chemistry. 8/21/2016, Vol. 45 Issue 31, p12292-12296. 5p.
Publication Year :
2016

Abstract

Photolysis of an iron tricarbonyl complex in the presence of 1-hexyne results in the activation of the terminal C–H bond to yield an iron–alkynyl species. The reaction proceeds through a single transition state with an activation enthalpy of 13.5 kcal mol−1. The resulting molecule may have potential as a C–C bond formation reagent. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14779226
Volume :
45
Issue :
31
Database :
Academic Search Index
Journal :
Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
117156378
Full Text :
https://doi.org/10.1039/c6dt02501c