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Iron(0) mediated C–H activation of 1-hexyne: a mechanistic study using time-resolved infrared spectroscopy.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 8/21/2016, Vol. 45 Issue 31, p12292-12296. 5p. - Publication Year :
- 2016
-
Abstract
- Photolysis of an iron tricarbonyl complex in the presence of 1-hexyne results in the activation of the terminal C–H bond to yield an iron–alkynyl species. The reaction proceeds through a single transition state with an activation enthalpy of 13.5 kcal mol−1. The resulting molecule may have potential as a C–C bond formation reagent. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 45
- Issue :
- 31
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 117156378
- Full Text :
- https://doi.org/10.1039/c6dt02501c