Back to Search Start Over

Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands.

Authors :
Hellou, Nora
Jahier-Diallo, Claire
Baslé, Olivier
Srebro-Hooper, Monika
Toupet, Loïc
Roisnel, Thierry
Caytan, Elsa
Roussel, Christian
Vanthuyne, Nicolas
Autschbach, Jochen
Mauduit, Marc
Crassous, Jeanne
Source :
Chemical Communications. 7/28/2016, Vol. 52 Issue 59, p9243-9246. 4p.
Publication Year :
2016

Abstract

The first helicene–NHC–iridium complexes have been prepared in enantiopure forms. Their stereochemical, electronic, and chiroptical features were characterized experimentally and via first-principles calculations, highlighting the helical and iridium-centered chirality. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
52
Issue :
59
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
116824607
Full Text :
https://doi.org/10.1039/c6cc04257k