Back to Search
Start Over
From discrete complex to 1-D coordination polymer by subtle variation of ligand donor: structures and electrical conductivities.
- Source :
-
Journal of Coordination Chemistry . Jun/Jul2016, Vol. 69 Issue 11-13, p1837-1843. 7p. 1 Diagram, 2 Charts, 3 Graphs. - Publication Year :
- 2016
-
Abstract
- A new coordination compound, [Cu(sphen)] (Hsphen = 2-sulfydryl-1,10-phenanthroline), as an analog of [Cu(ophen)] (Hophen = 1H-[1,10]phenanthrolin-2-one), is synthesized and characterized by single-crystal X-ray diffraction. While [Cu(ophen)] is a planar discrete complex showing strongπ–πstacking, [Cu(sphen)] is further connected by Cu–S bonds to form a one-dimensional coordination polymer. The bulk electrical conductivity of [Cu(sphen)] (5.0 × 10−3 S·cm−1) is ~3 orders of magnitude higher than that of [Cu(ophen)] (3.9 × 10−6 S·cm−1). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 69
- Issue :
- 11-13
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 116661956
- Full Text :
- https://doi.org/10.1080/00958972.2016.1190838