ChemInform Abstract: Towards a General Ruthenium-Catalyzed Hydrogenation of Secondary and Tertiary Amides to Amines.

Authors :: Cabrero‐Antonino, Jose R.
Alberico, Elisabetta
Junge, Kathrin
Junge, Henrik
Beller, Matthias
Source :: ChemInform. Jun2016, Vol. 47 Issue 25, pno-no. 1p.
Publication Year :: 2016
Abstract: A broad range of secondary and tertiary amides is hydrogenated to the corresponding amines under mild conditions using an in situ catalyst generated by combining [Ru(acac)3], 1,1,1-tris(diphenylphosphinomethyl)ethane (Triphos) and Yb(OTf)3. [ABSTRACT FROM AUTHOR]

Subjects :: *RUTHENIUM catalysts
*CATALYTIC hydrogenation
*AMINE synthesis
*BENZENE compound synthesis
*CATALYTIC reduction

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