Spiroborate-based dimeric assembly of oligo(ethylene glycol) end-capped with phenolic gallates.

Authors :: Yang, Jian-Ping
Wu, Xiao-Yu
Wang, Wan-Jun
Huang, Zuo-Gang
Jiang, Biao
Source :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Jun2016, Vol. 57 Issue 25, p2742-2745. 4p.
Publication Year :: 2016
Abstract: The synthesis of oligo(ethylene glycol) with biphenolic gallates as termini and their assembly to dimeric structures upon spiroborate formation are described. Complexation of these dimeric structures with alkali metal ions showed selectivity to lithium and potassium by tuning the length of the ethyleneoxy units. The methoxycarbonyl group on the dimeric compound could be manipulated in harsh conditions without destruction of the dimeric structure. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 00404039
Volume :: 57
Issue :: 25
Database :: Academic Search Index
Journal :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :: Academic Journal
Accession number :: 115797704
Full Text :: https://doi.org/10.1016/j.tetlet.2016.05.008

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