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Spiroborate-based dimeric assembly of oligo(ethylene glycol) end-capped with phenolic gallates.
- Source :
-
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry . Jun2016, Vol. 57 Issue 25, p2742-2745. 4p. - Publication Year :
- 2016
-
Abstract
- The synthesis of oligo(ethylene glycol) with biphenolic gallates as termini and their assembly to dimeric structures upon spiroborate formation are described. Complexation of these dimeric structures with alkali metal ions showed selectivity to lithium and potassium by tuning the length of the ethyleneoxy units. The methoxycarbonyl group on the dimeric compound could be manipulated in harsh conditions without destruction of the dimeric structure. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BORATES
*DIMERIC ions
*ETHYLENE glycol
*PHENOLS
*GALLATES
Subjects
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 57
- Issue :
- 25
- Database :
- Academic Search Index
- Journal :
- Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 115797704
- Full Text :
- https://doi.org/10.1016/j.tetlet.2016.05.008