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New One-dimensional Chain Compounds of [M (pdz) Cl 2 ] n (M=Cu(II), Fe(II), Mn(II); pdz = pyridazine and Their Magnetic Properties.
- Source :
-
Molecular Crystals & Liquid Crystals Science & Technology, Section A: Molecular Crystals & Liquid Crystals . 2002, Vol. 376 Issue 1, p283-288. 6p. - Publication Year :
- 2002
-
Abstract
- Three novel one-dimensional coordination polymers with pyridazine (pdz),[M (pdz) Cl 2 ] n (M = Cu (II) ( 1 ), Fe (II) ( 2 ), Mn (II) ( 3 )), were synthesized and characterized. All the compounds have one-dimensional zigzag chain structures. The copper ion in compound 1 has a planer coordination sphere with two bridging pdz ligands and two C1 - anions, while the metal ions in the other compounds have a distorted octahedral environment with pdz and Cl - groups both acting as bridges. The magnetic data of these compounds show antiferromagnetic interaction between the magnetic centers within the chains. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PYRIDAZINES
*METAL ions
*ANTIFERROMAGNETISM
Subjects
Details
- Language :
- English
- ISSN :
- 1058725X
- Volume :
- 376
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Molecular Crystals & Liquid Crystals Science & Technology, Section A: Molecular Crystals & Liquid Crystals
- Publication Type :
- Academic Journal
- Accession number :
- 11549557
- Full Text :
- https://doi.org/10.1080/10587250210752