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Deboronative cyanation of potassium alkyltrifluoroborates via photoredox catalysis.
- Source :
-
Chemical Communications . 5/21/2016, Vol. 52 Issue 41, p6793-6796. 4p. - Publication Year :
- 2016
-
Abstract
- A photoredox catalytic method was developed for the direct cyanation of alkyltrifluoroborates. This reaction provides a new and useful transformation of the easily available alkyltrifluoroborates. The photocatalytic reaction can tolerate a variety of functional groups with mild reaction conditions. Mechanistic investigations are consistent with the present reaction following a radical pathway. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 41
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 115305976
- Full Text :
- https://doi.org/10.1039/c6cc01530a