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Calibration of nylon organic chemical integrative samplers and sentinel samplers for quantitative measurement of pulsed aquatic exposures.
- Source :
-
Journal of Chromatography A . Jun2016, Vol. 1449, p109-117. 9p. - Publication Year :
- 2016
-
Abstract
- Environmental exposures often occur through short, pulsed events; therefore, the ability to accurately measure these toxicologically-relevant concentrations is important. Three different integrative passive sampler configurations were evaluated under different flow and pulsed exposure conditions for the measurement of current-use pesticides (n = 19), polyaromatic hydrocarbons (n = 10), and personal care products (n = 5) spanning a broad range of hydrophobicities (log Kow 1.5–7.6). Two modified POCIS-style samplers were investigated using macroporous nylon mesh membranes (35 μm pores) and two different sorbent materials (i.e. Oasis HLB and Dowex Optipore L-493). A recently developed design, the Sentinel Sampler (ABS Materials), utilizing Osorb media enclosed within stainless steel mesh (145 μm pores), was also investigated. Relatively high sampling rates ( Rs ) were achieved for all sampler configurations during the short eight-day exposure (4300–27 mL/d). Under flow conditions, median Rs were approximately 5–10 times higher for POCIS-style samplers and 27 times higher for Sentinel Samplers, as compared to static conditions. The ability of samplers to rapidly measure hydrophobic contaminants may be a trade off with increased flow dependence. Analyte accumulation was integrative under pulsed and continuous exposures for POCIS-style samplers with mean difference between treatments of 11% and 33%; however, accumulation into Sentinel Samplers was more variable. Collectively, results show that reducing membrane limitations allows for rapid, integrative accumulation of a broad range of analytes even under pulsed exposures. As such, these sampler designs may be suitable for monitoring environmental substances that have short aquatic half-lives. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00219673
- Volume :
- 1449
- Database :
- Academic Search Index
- Journal :
- Journal of Chromatography A
- Publication Type :
- Academic Journal
- Accession number :
- 115266187
- Full Text :
- https://doi.org/10.1016/j.chroma.2016.04.072