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New AB2 type two-photon absorption dyes for well-separated dual-emission: molecular preorganization based approach to photophysical properties.
- Source :
-
Tetrahedron . Jun2016, Vol. 72 Issue 22, p3040-3056. 17p. - Publication Year :
- 2016
-
Abstract
- A variety of AB2 type new target dyes containing two proton transfer segments ( o -hydroxy-phenyl-imino) are presented in this study. Furthermore, the corresponding reference molecules absent of hydroxy or imino groups are provided as well. Dual intramolecular hydrogen bonds in the target dyes are demonstrated by 1 H NMR spectra, X-ray single crystal analysis as well as one-photon absorption spectra. Linear emission properties (static and transient emission nature) and two-photon absorption optical properties of these target and reference dyes are determined in various media such as organic solvents, solid phase state as well as PMMA substrate. The results show that the new AB2 type target dyes can efficiently undergo internal proton transfer in the excited states under one-photon irradiation and near-infrared femtosecond laser two-photon irradiation, respectively, and thus they exhibit well-separated dual-emission. The molecular geometry optimization is performed for the analysis of the occurrence of internal proton transfer in the excited states of the target AB2 chromophores. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00404020
- Volume :
- 72
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- Tetrahedron
- Publication Type :
- Academic Journal
- Accession number :
- 115211912
- Full Text :
- https://doi.org/10.1016/j.tet.2016.04.024