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Electron-rich linear triplatinum complexes stabilized by a spinning tetraphosphine, tris(diphenylphosphinomethyl)phosphine.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 5/7/2016, Vol. 45 Issue 17, p7209-7214. 6p. - Publication Year :
- 2016
-
Abstract
- Linear triplatinum complexes with 48e−, [Pt3(μ-tdpmp)2(RNC)2](PF6)2 (R = 2,6-xylyl (3), tBu (4)), were synthesized by using a branched tetraphosphine, tris(diphenylphosphinomethyl)phosphine (tdpmp), and characterized by crystallographic and spectroscopic analyses to show their novel dynamic behaviour in the solution state, in which the linear Pt3 unit was stabilized by two spinning tetraphosphine ligands. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PHOSPHINE
*CRYSTALLOGRAPHY
*SPECTROSCOPIC imaging
*LIGANDS (Chemistry)
*PHOSPHINES
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 45
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 114825967
- Full Text :
- https://doi.org/10.1039/c6dt00624h