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Inside Back Cover: Introducing Chirality into Nonionic Dendritic Amphiphiles and Studying Their Supramolecular Assembly (Chem. Eur. J. 16/2016).

Authors :
Kumar, Sumit
Ludwig, Kai
Schade, Boris
von Berlepsch, Hans
Papp, Ilona
Tyagi, Rahul
Gulia, Monika
Haag, Rainer
Böttcher, Christoph
Source :
Chemistry - A European Journal. 4/11/2016, Vol. 22 Issue 16, p5795-5795. 1p.
Publication Year :
2016

Abstract

The chiral stereoisomers of new non‐ionic dendritic amphiphiles self‐assemble in aqueous solution towards helical ribbons with opposite handedness. However, in the case of the meso‐compound, cylindrical assemblies are observed, as illustrated. Modelling suggests that they consist of right‐ or left‐handed helical molecular strands in equal distribution. The hydrophobic core of such a cylinder is sized to accommodate the hydrophobic tails. Only the head groups and the aromatic platforms, which contribute high density in transmission electron microscopy (TEM), are shown for clarity. The paper discusses stereochemical aspects upon supramolecular assembly of these new dendritic amphiphiles. More information can be found in the Full Paper by C. Böttcher, et al. on page 5629 ff. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09476539
Volume :
22
Issue :
16
Database :
Academic Search Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
114439290
Full Text :
https://doi.org/10.1002/chem.201600645