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ChemInform Abstract: Highly Regioselective Palladium-Catalyzed Carboxylation of Allylic Alcohols with CO2.

Authors :
Mita, Tsuyoshi
Higuchi, Yuki
Sato, Yoshihiro
Source :
ChemInform. Mar2016, Vol. 47 Issue 16, pno-no. 1p.
Publication Year :
2016

Abstract

Allylic alcohols are carboxylated in the presence of a catalytic amount of PdCl2 and PPh3 using stoichiometric ZnEt2 as transmetalation agent under CO2 atmosphere. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*ALLYL alcohol
*CARBOXYLATION
*PALLADIUM catalysts
*REGIOSELECTIVITY (Chemistry)
*CARBON dioxide
*STOICHIOMETRY
*TRIPHENYLPHOSPHINE

Details

Language :
English
ISSN :
09317597
Volume :
47
Issue :
16
Database :
Academic Search Index
Journal :
ChemInform
Publication Type :
Academic Journal
Accession number :
114119615
Full Text :
https://doi.org/10.1002/chin.201616060
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