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Enantioselective iridium-catalyzed hydrogenation of β,β-disubstituted nitroalkenes.
- Source :
-
Chemical Communications . 4/4/2016, Vol. 52 Issue 26, p4812-4815. 4p. - Publication Year :
- 2016
-
Abstract
- An iridium complex with a newly prepared chiral spiro amino-phosphine ligand efficiently catalyzed the hydrogenation of both β-aryl-β-methyl-nitroalkenes and β-alkyl-β-methyl-nitroalkenes to the corresponding saturated nitroalkanes, which represents the first report of a chiral catalyst that exhibits high enantioselectivity for the challenging hydrogenation of β,β-dialkyl-nitroalkenes. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 26
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 113905931
- Full Text :
- https://doi.org/10.1039/c6cc01273f