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Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes.
- Source :
-
Journal of the American Chemical Society . 1/13/2016, Vol. 138 Issue 1, p52-55. 4p. - Publication Year :
- 2016
-
Abstract
- We report a metathesis reaction in which a nitrene fragment from an isocyanide ligand is exchanged with a nitrene fragment of an imido ligand in a series of niobium bis(imido) complexes. One of these bis(imido) complexes also promotes nitrene transfer to catalytically generate asymmetric dialkylcarbodiimides from azides and isocyanides in a process involving the Nb(V)/Nb(III) redox couple. [ABSTRACT FROM AUTHOR]
- Subjects :
- *NITRENES
*METATHESIS reactions
*NIOBIUM compounds
*LIGANDS (Chemistry)
*CATALYSIS
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 138
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 113302203
- Full Text :
- https://doi.org/10.1021/jacs.5b11287