Back to Search Start Over

Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone.

Authors :
Li, Xinjin
Zhao, Jingwei
Hu, Mingyou
Chen, Dingben
Ni, Chuanfa
Wang, Limin
Hu, Jinbo
Source :
Chemical Communications. 3/4/2016, Vol. 52 Issue 18, p3657-3660. 4p.
Publication Year :
2016

Abstract

A new method for the generation of the “PhSO2CF2Cu” species from readily available difluoromethyl phenyl sulfone (PhSO2CF2H) has been developed. The “PhSO2CF2Cu” reagent can be applied in (phenylsulfonyl)difluoromethylation of arylboronic acids, which affords a convenient approach to introducing the PhSO2CF2 group into aromatics. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
52
Issue :
18
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
113278356
Full Text :
https://doi.org/10.1039/c5cc10550a