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High-temperature heat capacity and thermodynamic properties of pyrovanadate PbVO and orthovanadate Pb(VO).
- Source :
-
Doklady Physical Chemistry . Jan2016, Vol. 466 Issue 1, p4-7. 4p. - Publication Year :
- 2016
-
Abstract
- The heat capacities of PbVO and Pb(VO) as a function of temperature in the range 350-965 K have been studied by the differential scanning calorimetry method. The C = f( T) curve for PbVO is described by the equation C = (230.76 ± 0.51) + (73.60 ± 0.50)×10 T − (18.38 ± 0.54)×10 T in the entire temperature range. For Pb(VO), there is a well-pronounced extreme point in the C = f( T) curve at T = 371.5 K, which is caused by the existence of a structural phase transition. The thermodynamic properties of the oxide compounds have been calculated. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00125016
- Volume :
- 466
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Doklady Physical Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 112967491
- Full Text :
- https://doi.org/10.1134/S0012501616010012