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Shape-selective separation of geraniol and nerol via noncovalent interactionswith β-cyclodextrin.
- Source :
-
Separation Science & Technology . 2016, Vol. 51 Issue 1, p168-180. 13p. - Publication Year :
- 2016
-
Abstract
- In this paper, selective separation of the isomeric compounds geraniol and nerol, based on the preferential affinity of β-cyclodextrin (β-CD) for geraniol was investigated. To demonstrate the potential application of β-CD for separation of geraiol from nerol, the structure of the inclusion complexes was characterized with various physico-chemical techniques. The selective noncovalent binding property of β-CD was confirmed by quantum-chemical calculations. For the mixture, which contains 50 wt% of geraniol and nerol, respectively, 96% of geraniol in complex can be obtained, and the similar separation efficiency was found after use for three times. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01496395
- Volume :
- 51
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Separation Science & Technology
- Publication Type :
- Academic Journal
- Accession number :
- 112507866
- Full Text :
- https://doi.org/10.1080/01496395.2015.1078357