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Photochemical H2 evolution from water catalyzed by a dichloro(diphenylbipyridine)platinum(ii) derivative tethered to multiple viologen acceptors.
- Source :
-
Chemical Communications . 1/25/2016, Vol. 52 Issue 7, p1385-1388. 4p. - Publication Year :
- 2016
-
Abstract
- A new single-component photocatalyst for the reduction of water to H2, a dichloro(dpbpy)platinum(ii) derivative (dpbpy = 4,4′-diphenyl-2,2′-bipyridine) tethered to four pendant viologen acceptors (1), is shown to exhibit twice higher photocatalytic efficiency than the previously reported dichloro(bpy)-platinum(ii) analog (2; bpy = 2,2′-bipyridine), consistent with the higher absorptivity of 1 at the metal-to-ligand charge transfer (1MLCT) band due to the larger π-conjugation in dpbpy relative to bpy. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 112296320
- Full Text :
- https://doi.org/10.1039/c5cc08044d