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A metal-mediated boron-centred isomerisation reaction via C–H activation.

Authors :
Braunschweig, Holger
Jimenez-Halla, J. Oscar C.
Radacki, Krzysztof
Shang, Rong
Source :
Chemical Communications. 11/28/2015, Vol. 51 Issue 92, p16569-16572. 4p.
Publication Year :
2015

Abstract

A heterocyclic manganese complex (4) derived from a carbonyl–borylene coupling reaction undergoes isomerisation, during which the former borylene moiety migrates to the cyclopentadienyl ligand and inserts into a C–H bond. This reaction and a computational study of its mechanism are discussed. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
51
Issue :
92
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
110768152
Full Text :
https://doi.org/10.1039/c5cc07681a