Mechanism of Formation of Hydrogen Trioxide (HOOOH) in the Ozonation of 1,2-Diphenylhydrazine and 1,2-Dimethylhydrazine: An Experimental and Theoretical Investigation.

Authors :: Plesničar, Božo
Tuttle, Tell
Cerkovnik, Janez
Koller, Jože
Cremer, Dieter
Source :: Journal of the American Chemical Society. 9/24/2003, Vol. 125 Issue 38, p11553-11564. 12p. 5 Diagrams, 4 Charts, 5 Graphs.
Publication Year :: 2003
Abstract: Discusses the mechanism of formation of hydrogen trioxide in the ozonation of 1,2-diphenylhydrazine and 1,2-dimethylhydrazine. Initiation of ozonation by the formation of an ozone-hydrazine complex; Evidence showing that radical recombination can lead to a hydrazine hydrotrioxide which decomposes quickly even at low temperatures.

Subjects :: *OXIDES
*OZONIZATION
*PHENYLHYDRAZINE
*METHYL hydrazine
*HYDRAZOBENZENE

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