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The Cage Structure of IndanCHF3 is Based on the Cooperative Effects of CH⋅⋅⋅π and CH⋅⋅⋅F Weak Hydrogen Bonds.

Authors :
Favero, Laura B.
Li, Weixing
Spada, Lorenzo
Evangelisti, Luca
Visentin, Giorgio
Caminati, Walther
Source :
Chemistry - A European Journal. Nov2015, Vol. 21 Issue 45, p15970-15973. 4p.
Publication Year :
2015

Abstract

The structural and energetic features of the CH⋅⋅⋅π interaction and the internal dynamics of the CHF3 group change drastically in going from benzeneCHF3 to indanCHF3, according to the analysis of the rotational spectrum of the latter complex generated in a supersonic expansion. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09476539
Volume :
21
Issue :
45
Database :
Academic Search Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
110484058
Full Text :
https://doi.org/10.1002/chem.201502981