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An asymmetric allylic alkylation reaction of 3-alkylidene oxindoles.
- Source :
-
Chemical Communications . 10/1/2015, Vol. 51 Issue 76, p14342-14345. 4p. - Publication Year :
- 2015
-
Abstract
- An efficient asymmetric allylic alkylation reaction with respect to 3-alkylidene oxindoles and racemic Morita–Baylis–Hillman carbonate has been achieved by using a chiral biscinchona alkaloid catalyst, which delivers the γ-substituted alkylideneoxindoles with a chiral tertiary center in moderate to good yields (up to 92%) and very good enantioselectivities (up to >99% ee). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 51
- Issue :
- 76
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 109360681
- Full Text :
- https://doi.org/10.1039/c5cc06182b