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Pulse-Driven Micro Gas Sensor Fitted with Clustered Pd/SnO2 Nanoparticles.

Authors :
Koichi Suematsu
Yuka Shin
Nan Ma
Tokiharu Oyama
Miyuki Sasaki
Masayoshi Yuasa
Tetsuya Kida
Kengo Shimanoe
Source :
Analytical Chemistry. 8/18/2015, Vol. 87 Issue 16, p8407-8415. 9p.
Publication Year :
2015

Abstract

Real-time monitoring of specific gas concentrations with a compact and portable gas sensing device is required to sense potential health risk and danger from toxic gases. For such purposes, we developed an ultrasmall gas sensor device, where a micro sensing film was deposited on a micro heater integrated with electrodes fabricated by the microelectromechanical system (MEMS) technology. The developed device was operated in a pulse-heating mode to significantly reduce the heater power consumption and make the device battery-driven and portable. Using clustered Pd/SnO2 nanoparticles, we succeeded in introducing mesopores ranging from 10 to 30 nm in the micro gas sensing film (area: φ 150 μm) to detect large volatile organic compounds (VOCs). The micro sensor showed quick, stable, and high sensor responses to toluene at ppm (parts per million) concentrations at 300 °C even by operating the micro heater in a pulse-heating mode where switch-on and -off cycles were repeated at one-second intervals. The high performance of the micro sensor should result from the creation of efficient diffusion paths decorated with Pd sensitizers by using the clustered Pd/SnO2 nanoparticles. Hence we demonstrate that our pulse-driven micro sensor using nanostructured oxide materials holds promise as a battery-operable, portable gas sensing device. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00032700
Volume :
87
Issue :
16
Database :
Academic Search Index
Journal :
Analytical Chemistry
Publication Type :
Academic Journal
Accession number :
109300463
Full Text :
https://doi.org/10.1021/acs.analchem.5b01767