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The electrochemical performance of nickel chromium oxide as a new anode material for lithium ion batteries.

Authors :
Ma, Jianjun
Ni, Shibing
Zhang, Jicheng
Yang, Xuelin
Zhang, Lulu
Source :
Electrochimica Acta. Sep2015, Vol. 176, p1420-1426. 7p.
Publication Year :
2015

Abstract

NiCr 2 O 4 is successfully prepared via hydrothermal pretreatment and subsequent sintering, which shows excellent electrochemical performance as a new anode material for lithium ion batteries with natural graphite adding and sodium alginate binder. At a specific current of 70 mA g −1 , it delivers charge and discharge capacities of 465.5 and 919.8 mAh g −1 in the initial cycle, which gradually increases along with cycle number owing to an electrochemical reconstruction in cycling. After 100 cycles, the charge and discharge capacities are 582.9 and 592.5 mAh g −1 , respectively. Furthermore, it is testified that natural graphite adding can effectively improve the electronic conductivity of the NiCr 2 O 4 electrode, and an appropriate amount of natural graphite is beneficial to improve the specific capacity and cycle stability of the electrode owing to a coordinated electrochemical reconstruction between NiCr 2 O 4 and natural graphite in cycling. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00134686
Volume :
176
Database :
Academic Search Index
Journal :
Electrochimica Acta
Publication Type :
Academic Journal
Accession number :
109279484
Full Text :
https://doi.org/10.1016/j.electacta.2015.07.071