Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal–organic framework.

Authors :: Wang, Juan
Wei, Zhen
Guo, Fengwan
Li, Chenyang
Zhu, Pengfei
Zhu, Wenhua
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 8/21/2015, Vol. 44 Issue 31, p13809-13813. 5p.
Publication Year :: 2015
Abstract: A luminescent homochiral uranyl succinate coordination polymer with unprecedented three-directional helices was synthesized hydrothermally via spontaneous symmetry breaking, and fully characterized. Its homochirality has been confirmed by singe crystal X-ray diffraction and solid state circular dichroism (CD) spectra. The polymer exhibited a Stokes shift greater than 180 nm. [ABSTRACT FROM AUTHOR]

Subjects :: *COORDINATION polymers synthesis
*CHEMICAL precursors
*CRYSTAL structure
*LUMINESCENCE
*METAL-organic frameworks
*SYMMETRY breaking
*CIRCULAR dichroism

Language :: English
ISSN :: 14779226
Volume :: 44
Issue :: 31
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 108744686
Full Text :: https://doi.org/10.1039/c5dt02111a

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