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Ligandless C-C bond formation via.

Authors :
Hoseini, S. Jafar
Zarei, Atiyeh
Rafatbakhsh Iran, Hajar
Source :
Applied Organometallic Chemistry. Aug2015, Vol. 29 Issue 8, p489-494. 6p.
Publication Year :
2015

Abstract

PdPtZn and PdZn nanoparticle (NP) were synthesized by the reduction of [PdCl2(cod)], [PtCl2(cod)] (cod = cis, cis-1,5-cyclooctadiene) and [Zn(acac)2] (acac = acetylacetonate) complexes at an oil-water interface. The structure and morphology of the as-prepared NPs were characterized with X-ray diffraction, transmission and energy dispersive analysis of X-rays. of the prepared NPs was investigated in the in H2O-EtOH and various micellar media systems such as cetyltrimethylammonium bromide (cationic surfactant), sodium dodecylsulfate (anionic surfactant) and Pluronic P123 (non-ionic surfactant). PdPtZn and PdZn exhibited higher compared to Pd in the due to the appropriate interaction between palladium, platinum and zinc metals. Copyright © 2015 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
02682605
Volume :
29
Issue :
8
Database :
Academic Search Index
Journal :
Applied Organometallic Chemistry
Publication Type :
Academic Journal
Accession number :
108544016
Full Text :
https://doi.org/10.1002/aoc.3318