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Stabilization of cubic Sr2FeMoO6 through topochemical reduction.

Authors :
Taylor, Daniel D.
Schreiber, Nathaniel J.
Brown, Craig M.
Arevalo-Lopez, Angel M.
Rodriguez, Efrain E.
Source :
Chemical Communications. 8/7/2015, Vol. 51 Issue 61, p12201-12204. 4p.
Publication Year :
2015

Abstract

Sr2FeMoO6 has been extensively studied for application in spintronic devices. Through the topochemical de-intercalation of oxygen anions with metal hydride reduction, we demonstrate that the high temperature cubic phase is stabilized, at room temperature, whilst leaving the magnetic ordering intact. Synchrotron X-ray and neutron powder diffraction were used to characterize the structure and stoichiometry of the reduced oxide. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
51
Issue :
61
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
108462165
Full Text :
https://doi.org/10.1039/c5cc04145g