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Synthesis, structure and properties of a neutral zincophosphate monomer decorated with 2,<f>2′</f>-bipyridine ligands

Authors :
Lin, Zhi-En
Zhang, Jie
Zheng, Shou-Tian
Yang, Guo-Yu
Source :
Inorganic Chemistry Communications. Aug2003, Vol. 6 Issue 8, p1035. 4p.
Publication Year :
2003

Abstract

A neutral zincophosphate monomer [Zn(2,&lt;f&gt;2′&lt;/f&gt;-bipy)]2(H2PO4)4 has been synthesized under hydrothermal condition in the presence of 2,&lt;f&gt;2′&lt;/f&gt;-bipyridine ligands. The structure consists of a 4-membered ring formed by vertex-sharing ZnO3N2 square pyramids and H2PO4 tetrahedra, with two H2PO4 groups hanging from the zinc atoms. This compound exhibits intense photoluminescence upon photoexcitation at 388 nm. [Copyright &amp;y&amp; Elsevier]

Details

Language :
English
ISSN :
13877003
Volume :
6
Issue :
8
Database :
Academic Search Index
Journal :
Inorganic Chemistry Communications
Publication Type :
Academic Journal
Accession number :
10357704
Full Text :
https://doi.org/10.1016/S1387-7003(03)00178-3