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A New Chiral Coordination Polymer with Large Cavities of [Cu(NA)(DMF)]: Synthesis, Structural and Magnetic Property.
- Source :
-
Journal of Inorganic & Organometallic Polymers & Materials . Jul2015, Vol. 25 Issue 4, p1006-1010. 5p. - Publication Year :
- 2015
-
Abstract
- A new metal-organic architectures, [Cu(NA)(DMF)] ( 1), where NA stands for nicotinic acid, has been successfully synthesized and characterized by elemental analysis, IR, TG analysis and single crystal X-ray diffraction. Single-crystal X-ray diffraction reveals that the Cu centers adopt a distorted square pyramidal geometry, and nicotinic acid acts as a bidentate ligand connected with the adjacent two Cu atoms by the pyridyl and carboxylate groups to form a 3D framework structure. The framework exhibits open chiral channels with coordinated DMF molecules inside it. In addition, the magnetic properties have also been studied. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15741443
- Volume :
- 25
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Journal of Inorganic & Organometallic Polymers & Materials
- Publication Type :
- Academic Journal
- Accession number :
- 103244588
- Full Text :
- https://doi.org/10.1007/s10904-015-0198-1