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Synthesis of Bench-Stable Diarylmethylium Tetrafluoroborates.
- Source :
-
Journal of Organic Chemistry . 5/1/2015, Vol. 80 Issue 9, p4791-4796. 6p. - Publication Year :
- 2015
-
Abstract
- A representative number of bench-stable nonsymmetric diarylcarbenium tetrafluoroborates have been isolated via the direct coupling of aryl (or heteroaryl) aldehydes and N-heteroarenes and fully characterized. They have proven to be highly stable in the presence of both EDG and EWG substituents. An (E)-iminium vinylogous substructure has been shown as the common cation scaffold by X-ray analysis and by NOE determination. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 80
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 102689410
- Full Text :
- https://doi.org/10.1021/acs.joc.5b00418