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Bovine Serum Albumin-Mediated Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate.

Authors :
Wada, Takehiko
Nishijima, Masaki
Fujisawa, Tai
Sugahara, Norimitsu
Mori, Tadashi
Nakamura, Asao
Inoue, Yoshihisa
Source :
Journal of the American Chemical Society. 6/25/2003, Vol. 125 Issue 25, p7492. 2p. 1 Chart, 3 Graphs.
Publication Year :
2003

Abstract

Proposes a dynamic supramolecular photochirogenesis of 2-anthracenecarboxylate (AC) using bovine serum albumin (BSA). Analysis of the complexation behavior of AC by BSA; Examination of supramolecular interaction by circular dichroism spectral titration; Detection of four binding sites in BSA for AC of different affinity, stoichiometry and chiral environment.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
25
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
10196967
Full Text :
https://doi.org/10.1021/ja034641g