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[AEPH2][GeSb2S6]·CH3OH: a thiogermanate–thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb3S11} unit and exhibiting the ability of photocatalytic degradation of organic dye

Authors :
Feng, Mei-Ling
Hu, Chun-Li
Wang, Kai-Yao
Du, Cheng-Feng
Huang, Xiao-Ying
Source :
CrystEngComm. 2013, Vol. 15 Issue 25, p5007-5011. 5p.
Publication Year :
2013

Abstract

A new thiogermanate–thioantimonate, namely, [AEPH2][GeSb2S6]·CH3OH (1) (AEP = N-(2-aminoethyl)piperazine) has been solvothermally synthesized, whose structure features a one-dimensional anionic ribbon of [GeSb2S6]n2n− built of the firstly observed tetranuclear {GeSb3S11} cluster as secondary building unit. The photocatalytic study indicated that 1 was able to degrade Rhodamine B under visible irradiation. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14668033
Volume :
15
Issue :
25
Database :
Academic Search Index
Journal :
CrystEngComm
Publication Type :
Academic Journal
Accession number :
100903094
Full Text :
https://doi.org/10.1039/c3ce40143j